THE STEREOCHEMISTRY OF ORGANOMETALLIC COMPOUNDS. XXXVI. REGIO- AND STEREO-CHEMICAL CONTROL IN THE NICKEL-CATALYSED HYDROCYANATION OF SILYLALKYNES

DOI: 10.1016/0022-328X(85)87381-2

Source and publish data:

Journal of Organometallic Chemistry p. 375 - 382 (1985)

Update date:2022-08-11

Topics:

Authors:

Fitzmaurice, Neil J.

Jackson, W. Roy

Perlmutter, Patrick

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Article abstract of DOI:10.1016/0022-328X(85)87381-2

The regioselectivity of hydrocyanation of silylalkynes can be controlled by varying the size of the groups attached to silicon leading, for example, to efficient preparations of E-3-trialkylsilyl-2-alkyl-2-alkenenitriles.High yields of the silylalkene nitriles can be obtained by using either acetone cyanohydrin or hydrogen cyanide as reagents.

Full text of DOI:10.1016/0022-328X(85)87381-2

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