Tetrahedron p. 2775 - 2786 (2018)
Update date:2022-08-16
Topics:
Cowper, Paul
Pockett, Adam
Kociok-K?hn, Gabriele
Cameron, Petra J.
Lewis, Simon E.
We report the synthesis of five new azulene containing dyes, having D-π-A type structures. These dyes are synthesised using a sulfonium salt cross-coupling reaction. The dyes have been evaluated spectroscopically, electrochemically, crystallographically, and as sensitizers in dye-sensitized solar cells. We propose a rationale for the dyes’ spectroscopic properties and performance in cells, based on conformational data derived from their crystal structures.
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