Journal of Physical Chemistry p. 7606 - 7611 (1993)
Update date:2022-08-11
Topics:
Wallington, Timothy J.
Hurley, Michael D.
Schneider, William F.
Sehested, Jens
Nielsen, Ole John
Evidence is presented that CF3O radicals react with H2O in the gas phase at 296 K to give CF3OH and OH radicals.This reaction is calculated to be exothermic by 1.7 kcal mol-1 implying a surprisingly strong CF3O-H bond energy of 120 +/- 3 kcal mol-1.Results from a relative rate experimental study suggest that the rate constant for the reaction of CF3O radicals with H2O lies in the range (0.2-40) x 10-17 cm3 molecule-1 s-1.Implications for the atmospheric chemistry of CF3O radicals are discussed.
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