Russian Chemical Bulletin p. 2049 - 2052 (1993)
Update date:2022-08-10
Topics:
Koehler, K. F.
Zaddach, H.
Kadorkina, G. K.
Voznesenskii, V. N.
Chervin, I. I.
Kostyanovsky, R. G.
The structure of azimexone (3), the product of the reaction of 2-cyanoaziridine with acetone, was confirmed on the basis of 1H and 13C NMR spectra.The formation of this product is accounted for by the α-aziridinoalkylating action of an intermediate containing a good leaving iminoyloxy group.Similar reactions were observed for 1-chloromethylaziridine and a 1-aziridinylmethylammonium salt (6), but not for 1-methoxymethylaziridine (7) and 1-aziridinemethanol. - Key words: 2-(2-cyanoaziridino)-2-(2-carbamoylaziridino)propane; 1-tert-butyl-2-carbamoylaziridine; α-1-aziridinoalkylation; 1H and 13C NMR spectra.
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