Tetrahedron Letters p. 6912 - 6915 (2013)
Update date:2022-08-10
Topics:
Mane, Rajendra S.
Nordeman, Patrik
Odell, Luke R.
Larhed, Mats
A novel and convenient protocol for the synthesis of N-cyanobenzamides starting from readily available aryl halides and cyanamide via palladium-catalyzed aminocarbonylation has been developed. The protocol utilizes Mo(CO)6 as the CO source or CO(gas) and affords the desired N-cyanobenzamides in moderate to good yields.
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