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Favorskii-Type Rearrangement of α,α'-Dihalo Ketones with Sodiomalonates Leading to Conjugated Enone Derivatives

DOI: 10.1246/bcsj.60.2295

Source and publish data:

Bulletin of the Chemical Society of Japan p. 2295 - 2297 (1987)

Update date:2022-08-29

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Authors:

Sakai, TakashiSakai, Takashi

Ishikawa, MutsumiIshikawa, Mutsumi

Amano, EiichiroAmano, Eiichiro

Utaka, MasanoriUtaka, Masanori

Takeda, AkiraTakeda, Akira

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Article abstract of DOI:10.1246/bcsj.60.2295

A new synthetic method of conjugated enones by the use of carbanion-induced Favorskii-type rearrangement is described.The reaction of α,α'-dihalo ketones R1R2-(X)CC(O)CH2X with sodiomalonates Na+-CR3(

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Full text of DOI:10.1246/bcsj.60.2295

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