Bulletin of the Chemical Society of Japan p. 307 - 308 (1994)
Update date:2022-08-29
Topics:
Suyama, Takayuki
Ozawa, Nobuyuki
Suzuki, Noriyuki
O-ethyl S-methyl N-cyanocarbonimidothioate reacted with hydroxylamine to give 5-amino-3-ethoxy-1,2,4-oxadiazole, whereas diethyl N-cyanocarbonimidate reacted to give 3-amino-5-ethoxy-1,2,4-oxadiazole.The reaction of ethyl N-cyanocarbamate or S-methyl N-cyanothiocarbamate with hydroxylamine afforded 3-amino-1,2,4-oxadiazol-5(4H)-one.
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