Journal of the Chemical Society. Chemical communications p. 1826 - 1828 (1993)
Update date:2022-08-15
Topics:
Fawcett, John
Harger, Martin J. P.
Russell, David R.
Sreedharan-Menon, Ramesh
Methoxide-induced rearrangement of the α-bromophosphonamidate 1b (X=Br) gives two products, 2b and 3b, corresponding to breakdown of the intermediate azaphosphiridine oxide 4b by nucleophilic attack at phosphorus, and cleavage of the P-N bond (major pathway) with inversion of configuration or the P-C bond (minor pathway) with retention; this suggests involvement of a five-coordinate species as an intermediate, not merely as a transition state.
View MoreContact:86-371-63655023
Address:No.85,jinshui road,zhengzhou,China
Taizhou Crene Biotechnology co.ltd
Contact:86-576-88813233 88205808
Address:Economic Developed Zone of Taizhou Zhejiang China
Contact:+91 9963263336
Address:Plot#146A, IDA Mallapur, Hyderabad - 500072
Chongqing Werlchem Fine Chemical Co. Ltd
Contact:+86-23-67521957
Address:NO.15,Fortune Road,Yubei District,401121,Chongqing,China
Meryer (Shanghai) Chemical Technology Co., Ltd.
website:http://www.meryer.com/cn/index/
Contact:+86-755-86170518
Address:Minhang,Shanghai, China
Doi:10.1016/0039-128X(80)90016-1
(1980)Doi:10.1016/S0040-4039(97)10053-3
(1997)Doi:10.1055/s-0035-1561567
(2016)Doi:10.1039/c1cc12544c
(2011)Doi:10.1021/ja00067a091
(1993)Doi:10.1007/s10847-014-0450-2
(2015)
