Journal of the Chemical Society. Chemical communications p. 1826 - 1828 (1993)
Update date:2022-08-15
Topics:
Fawcett, John
Harger, Martin J. P.
Russell, David R.
Sreedharan-Menon, Ramesh
Methoxide-induced rearrangement of the α-bromophosphonamidate 1b (X=Br) gives two products, 2b and 3b, corresponding to breakdown of the intermediate azaphosphiridine oxide 4b by nucleophilic attack at phosphorus, and cleavage of the P-N bond (major pathway) with inversion of configuration or the P-C bond (minor pathway) with retention; this suggests involvement of a five-coordinate species as an intermediate, not merely as a transition state.
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