Novel Chlorotrimethylsilane Catalyzed Stereoselective Deconjugation of β-Bromo (or Iodo) Substituted α,β-Unsaturated Acyclic Ketone

DOI: 10.1016/0040-4039(94)88517-6

Source and publish data:

Tetrahedron Letters p. 9585 - 9588 (1994)

Update date:2022-09-26

Topics:

Authors:

Luo, Fen-Tair

Hsieh, Li-Chen

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Article abstract of DOI:10.1016/0040-4039(94)88517-6

TMSCl catalyzed stereoselective isomerization (deconjugation) of β-substituted α,β-unsaturated ketones to the corresponding (Z)-β,γ-unsaturated ketones and its mechanism studies are described.

Full text of DOI:10.1016/0040-4039(94)88517-6

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