New Chiral Anisotropic Reagents, NMR Tools to Elucidate the Absolute Configuration of Long-chain Organic Compounds

DOI: 10.1016/S0040-4039(00)73366-1

Source and publish data:

Tetrahedron Letters p. 4397 - 4400 (1994)

Update date:2022-08-22

Topics:

Authors:

Kusumi, Takenori

Takahashi, Haruko

Xu, Ping

Fukusima, Toshiro

Asakawa, Yoshinori

et al. et al.

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Article abstract of DOI:10.1016/S0040-4039(00)73366-1

Modified Mosher's method has been extended by use of 9-anthranylmethoxyacetic acid (9ATMA) and 2-naphthylmethoxynaphthylacetic acid (2NMA) instead of MTPA of the conventional method.Anisotropic effects of these reagents are much greater than that of MTPA, and the reagents have been shown to useful especially to determine the absolute configurations of the secondary alcohols involved in long-chain componds.

Full text of DOI:10.1016/S0040-4039(00)73366-1

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