The phosphorylation of alkenes promoted with the VIB group metals' carbonyl complexes

Full text of DOI:10.1080/10426500213408

Phosphorus, Sulfur, and Silicon and the Related Elements
ISSN: 1042-6507 (Print) 1563-5325 (Online) Journal homepage: http://www.tandfonline.com/loi/gpss20
The Phosphorylation of Alkenes Promoted with
the VIB Group Metals' Carbonyl Complexes
Rafael A. Cherkasov , Arcady I. Kuramshin & Helen S. Kuramshina
To cite this article: Rafael A. Cherkasov , Arcady I. Kuramshin & Helen S. Kuramshina
(2002) The Phosphorylation of Alkenes Promoted with the VIB Group Metals' Carbonyl
Complexes, Phosphorus, Sulfur, and Silicon and the Related Elements, 177:8-9, 1989-1989,
DOI: 10.1080/10426500213408
To link to this article: http://dx.doi.org/10.1080/10426500213408
Published online: 27 Oct 2010.
Submit your article to this journal
Article views: 9
View related articles
Full Terms & Conditions of access and use can be found at
http://www.tandfonline.com/action/journalInformation?journalCode=gpss20
Download by: [La Trobe University]
Date: 31 May 2016, At: 02:42

Phosphorus, Sulfur and Silicon, 2002, Vol. 177:1989
C
Copyright 2002 Taylor & Francis
1042-6507/02 $12.00 + .00
DOI: 10.1080/10426500290094396
THE PHOSPHORYLATION OF ALKENES PROMOTED
WITH THE VIB GROUP METALS’
CARBONYL COMPLEXES
Rafael A. Cherkasov, Arcady I. Kuramshin,
and Helen S. Kuramshina
Kazan State University, Kazan, Russia
(Received July 29, 2001; accepted December 25, 2001)
The phosphonates can be prepared in the direct interaction of the dial-
kylphosphytes with alkenes, promoted with the VIB group metals’ car-
bonyl complexes’ derivatives. The catalytic effect is observed either
when the alkene reacts with the organometallics forming -complex
or when dialkylphosphite reacts forming the active intermediate (II).
SCHEME 1
The catalytic yield of (I) is 40–80% according on the dialkylphosphite
or 500–1000% on the hexacarbonylmetall(0) taken as catalyst.
This work is supported by the joint program of CRDF and Russian Ministry of Ed-
ucation, “Basic Research & High Education” (grant REC 007); and Russian Ministry of
Education program, “The Investigations of the High School at the Frontier of the Science
& Techniques” (grant 0.2.01.009).
Address correspondence to Rafael A. Cherkasov, Kazan State University, Chemistry
Department, 420008, Kremlyovskaya 18, Kazan, Russia.
E-mail: rafael.cherkasov@ksu.ru
1989