Syntheses, Kinetics, and Mechanism of Ligand Substitution Reactions of 17-Electron Cyclopentadienyl and Pentadienyl Vanadium Carbonyl Complexes

DOI: 10.1021/ja00250a018

Source and publish data:

Journal of the American Chemical Society p. 4860 - 4869 (1987)

Update date:2022-08-17

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Authors:

Kowaleski, Ruth M.

Basolo, Fred

Trogler, William C.

Gedridge, Robert W.

Newbound, Timothy D.

Ernst, Richard D.

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Article abstract of DOI:10.1021/ja00250a018

Reported are the syntheses of bis(η⁵-pentadienyl)vanadium carbonyls and corresponding triethylphosphine compounds.The CO substitution lability in the complexes (η⁵-L)2VCO (L = C5H5, C5Me5, C5H7, 2,4-C7H11) was investigated.The exchan

Full text of DOI:10.1021/ja00250a018

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