Journal of Organic Chemistry p. 5264 - 5267 (1989)
Update date:2022-08-23
Topics:
Baldwin, John E.
Reddy, V. Prakash
1(E)-Deuteriobutadiene and cyclopropene react at 0 deg C to give 2-endo-deuteriobicyclo<4.1.0>hept-3-ene; 1(Z)-deuteriobutadiene leads to the 2-exo-deuterio bicyclic product.Analysis of these products through 2H NMR spectroscopy reveals complete stereospecificity, indicating that the transition structure having an endo orientation of diene and cyclopropene is strongly favored over the alternative exo geometry.
View More
Shandong Xinke Petrochemical Co., Ltd.
Contact:+86-546-7277016
Address:Gudao Industrial Park, Hekou District, Dongying, Shandong Province, China
TAIZHOU XINGCHENG CHEMPHARM CO.,LTD.
Contact:0086-0576-88551200,88886292 ,88880039
Address:B Area. 10 Floor.Yaodadasha. 289#.Shifu Road.Taizhou.Zhejiang.China
Shanghai Sunwise Chemical Co., Ltd
website:http://www.sunwisechem.com
Contact:86-021-33883180
Address:Room 10E, Building G, Westlink Center, No. 2337 Gudai Road, Minhang District, Shanghai, China PC: 201100
website:http://www.guarson.com
Contact:+86-523-88059600,+86-13805268803
Address:Room B1006,Yafang Building,Jiangyan Avenue,Jiangyan District, Taizhou City,Jiangsu,China
Contact:+86-0311-84455288-844
Address:Mayu Industrial Park, Jinzhou, Hebei, China.
Doi:10.1016/0022-5088(88)90219-6
(1988)Doi:10.1039/c3dt51599k
(2014)Doi:10.1021/j100072a007
(1994)Doi:10.1039/c3ra46314a
(2014)Doi:10.1016/j.saa.2015.05.022
(2015)Doi:10.1002/1522-2675(200208)85:8<2300::AID-HLCA2300>3.0.CO;2-B
(2002)
