Journal of Organic Chemistry p. 5264 - 5267 (1989)
Update date:2022-08-23
Topics:
Baldwin, John E.
Reddy, V. Prakash
1(E)-Deuteriobutadiene and cyclopropene react at 0 deg C to give 2-endo-deuteriobicyclo<4.1.0>hept-3-ene; 1(Z)-deuteriobutadiene leads to the 2-exo-deuterio bicyclic product.Analysis of these products through 2H NMR spectroscopy reveals complete stereospecificity, indicating that the transition structure having an endo orientation of diene and cyclopropene is strongly favored over the alternative exo geometry.
View More
website:http://www.dulynet.com/
Contact:025-84699383 -8003
Address:Room 503, Building 2, Chuangxinhui, No. 61 Wenjing Road, High-tech Development Zone, Pukou District, Nanjing City, Jiangsu Province Nanjing, Jiangsu
Shangyu Sanhechemicals Co.,LTD.
Contact:86-0571-56696839
Address:Num.2952,Nanhuan Road,Binjiang District,Hangzhou,China
Suzhou Wedo Chemicals Co., Ltd.
Contact:86 512 58100425
Address:Zonger Road, DongSha Industry Park , Zhangjiagang, Jiangsu, China
chengdu firsterchem Pharmaceutical Co., Ltd.
Contact:028-66825849
Address:chengdu
Contact:+86-0760-85282375
Address:zhongjing road,zhongshan torch hi-tech industrial development zone
Doi:10.1016/0022-5088(88)90219-6
(1988)Doi:10.1039/c3dt51599k
(2014)Doi:10.1021/j100072a007
(1994)Doi:10.1039/c3ra46314a
(2014)Doi:10.1016/j.saa.2015.05.022
(2015)Doi:10.1002/1522-2675(200208)85:8<2300::AID-HLCA2300>3.0.CO;2-B
(2002)
