Journal of Organic Chemistry p. 5264 - 5267 (1989)
Update date:2022-08-23
Topics:
Baldwin, John E.
Reddy, V. Prakash
1(E)-Deuteriobutadiene and cyclopropene react at 0 deg C to give 2-endo-deuteriobicyclo<4.1.0>hept-3-ene; 1(Z)-deuteriobutadiene leads to the 2-exo-deuterio bicyclic product.Analysis of these products through 2H NMR spectroscopy reveals complete stereospecificity, indicating that the transition structure having an endo orientation of diene and cyclopropene is strongly favored over the alternative exo geometry.
View More
Contact:86-379-63338609
Address:Jiudian Village,Deting Town,Song County,Luoyang
Junkai (Tianjin) Chemical Co., Ltd.
website:http://www.junkaichem.com
Contact:86-22-85689515
Address:Room 8-501, Building K2, The Hi-Tech Green Industrial Base, No.6, 6th Road, Hi-Tech Development Road, Tianjin Hi-Tech IndustrialPark, Tianjin, China.
Hangzhou J&H Chemical Co., Ltd.
website:http://www.jhechem.com/
Contact:+86-571-87396432
Address:No.200 Zhenhua Rd.Xihu Industrial Park, Hangzhou 310030, China
XI'AN CHUKANG BIOTECHNOLOGY CO.,LTD
Contact:29-63685658 63685359
Address:Room 3-1202,Building 1,Oriental oasis,East of Xianning Road,Xi'an,Shaanxi 710043 P.R.China
Jiaxing Carry Bio-Chem Technology Co.,Ltd
website:http://www.carrybiotech.com
Contact:0573-82788958
Address:Add.Fl 3th, Pharm Vally,Kaichuang Rd, Xiuzhou District, Jiaxing, Zhejiang,314031,China
Doi:10.1016/0022-5088(88)90219-6
(1988)Doi:10.1039/c3dt51599k
(2014)Doi:10.1021/j100072a007
(1994)Doi:10.1039/c3ra46314a
(2014)Doi:10.1016/j.saa.2015.05.022
(2015)Doi:10.1002/1522-2675(200208)85:8<2300::AID-HLCA2300>3.0.CO;2-B
(2002)
