Tetrahedron p. 13771 - 13782 (1998)
Update date:2022-08-10
Topics:
Russell, Jamie
Roques, Nicolas
Common bases (alcoholate, dimsyl anion or amide) are able to deprotonate trifluoromethane to form a trifluoromethyl anion equivalent. In this reaction DMF plays a crucial role of stabilisation Trifluoromethyl aryl alcohols, ketones or sulfides can be obtained in good yields with the new reagent CF3H/Base/DMF.
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