Helvetica Chimica Acta p. 168 - 176 (1983)
Update date:2022-08-17
Topics:
Camenzind, Hugo
Voegeli, Ulrich Christian
Keese, Reinhart
Reductive elimination at 1,2exo-diiodonorbornane (6) was induced by Collman's reagent.Surprisingly, 1,2endo-diiodonorbornane (9) and 1-iodo-2endo-trifluoromethylsulfonyloxy-norbornane (10b) lead only to reactions of the substituent in 2-position.Mechanistic aspects are related to the reactions of monosubstituted iodonorbornanes with Collman's reagent.
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Doi:10.1021/jo01330a025
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