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; Ag was modeled as Ag2 by removing the OAc ligands from
Ag2(OAc)2. Energies for INT-9 were calculated as for example ΔG°rxn
(INT-9) = ΔG°INT‑9 + ΔG°Ag2 − (2 ΔG°AgOAc + ΔG°6). Ag2 is clearly
not an accurate representation for elemental Ag; as a result, the
absolute values for ΔG°rxn for steps involving AgOAc are too high and
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dx.doi.org/10.1021/cs400656q | ACS Catal. 2013, 3, 2421−2429