Tetrahedron Letters p. 3377 - 3380 (1995)
Update date:2022-08-23
Topics:
Hosoya, Takamitsu
Hasegawa, Takayuki
Kuriyama, Yokusu
Suzuki, Keisuke
The first observation of the stereospecificity in the benzyne-olefin [2 + 2] cycloaddition is described. The key points reside in (1) the efficient method for generating benzyne species by the halogen-lithium exchange reaction of ortho-halo aryl triflates
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