Tetrahedron Letters p. 1409 - 1412 (1989)
Update date:2022-08-17
Topics:
Symons, Martyn C.R.
Bowman, Russell
Taylor, Peter F.
Exposure of various bromo- and iodo-imidazoles as dilute solutions in methanol or methyltetrahydrofuran at 77 K to 60Co γ-rays resulted in electron addition to yield major species which were not the expected ?* radical anions but ?* radical anions, the SOMO being primarily the C-hal ?* orbital with little delocalisation.
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