Total synthesis of both enantiomers of 15-Oxopuupehenol methylendioxy derivatives

DOI: 10.1016/S0040-4039(97)01683-3

Source and publish data:

Tetrahedron Letters p. 7249 - 7252 (1997)

Update date:2022-08-17

Topics:

Authors:

Arjona, Odon

Garranzo, Maria

Mahugo, Jesus

Maroto, Eduardo

Plumet, Joaquin

Saez, Beatriz

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Article abstract of DOI:10.1016/S0040-4039(97)01683-3

The total synthesis of both enantiomers of puupehenol and 15-oxopuupehenol as methylenedioxy derivatives is described. The key steps of the synthesis are the regioselective transformation of 10 to 11 and the stereoselective cyclization of 12 to 13.

Full text of DOI:10.1016/S0040-4039(97)01683-3

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