Liquid Crystalline Catalysis. 2. Sulfonate Ester Rearrangements Induced in Solution by the Ordered Structure of a Smectic B Solvent

DOI: 10.1021/ja00315a033

Source and publish data:

Journal of the American Chemical Society p. 653 - 656 (1984)

Update date:2022-08-11

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Authors:

De Maria, Paolo

Lodi, Andrea

Samori, Bruno

Rustichelli, Franco

Torquati, Giuseppe

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Article abstract of DOI:10.1021/ja00315a033

We have used a smectic B (Sm B) solvent to obtain experimental evidence of the catalytic effect of tightly ordered mesomorphic structures.To accomplish this we have selected two reactions with severe orientational demand in the transition state.The liquid

Full text of DOI:10.1021/ja00315a033

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