Ultrasonically Dispersed Potassium in Organic Synthesis. Water-Acceleration in Reductive C-S Bond Cleavage Reactions

DOI: 10.1016/0040-4039(91)80830-Y

Source and publish data:

Tetrahedron Letters p. 3551 - 3554 (1991)

Update date:2022-08-10

Topics:

Authors:

Chou, Ta-shue

Hung, Shao-Hwa

Peng, Man-Li

Lee, Shwu-Jiaun

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Article abstract of DOI:10.1016/0040-4039(91)80830-Y

The slow addition of a pre-measured amount of water in THF can greatly enhance the UDP induced C-S bond cleavage reactions of cyclic sulfones.This reaction can be used in the synthesis of open chain sulfones with γ-, δ- or ε-deuteration.

Full text of DOI:10.1016/0040-4039(91)80830-Y

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