Photolysis of matrix-isolated CF3C(O)SH and CF3C(O)SCl

DOI: 10.1016/S0022-2860(96)09639-1

Source and publish data:

Journal of Molecular Structure p. 171 - 175 (1997)

Update date:2022-08-10

Topics:

Authors:

Ulic Ulic

Gobbato Gobbato

Della Vedova

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Article abstract of DOI:10.1016/S0022-2860(96)09639-1

Perfluoroacetylthiol, CF₃C(O)SH, and perfluoroacetylsulphenyl chloride, CF₃C(O)SCl, were irradiated in an inert gas matrix to produce CF₃SH and CO, and CF₃SCl, CF₃Cl, CO and SCO, respectively. The compounds are identified by evaluating the apparition of new bands in the FTIR spectrum of the matrix-isolated substance. The results are compared with related studies of similar compounds taking into account both the irradiation and the stability of the formed products.

Full text of DOI:10.1016/S0022-2860(96)09639-1

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