Journal of Physical Chemistry p. 6334 - 6336 (1987)
Update date:2022-08-23
Topics:
Friedrich, H. Bruce
Burton, Donald J.
Tardy, D. C.
Infrared multiphoton excitation of tetrafluorocyclopropene (TFCP) leads to the unexpected formation of tetrafluoroallene (TFA) and tetrafluoropropyne (TFP).The ratio of TFP to TFA formed in the reaction is independent of fluence and pressure, and no other products are formed.The conversion per pulse increases as the pressure of TFCP increases but decreases as the pressure of a buffer gas or the products increases.The apparent intramolecular 1,2-fluorine migration required to form the products is discussed in terms of both unimolecular and bimolecular processes.
View More
Contact:+86-633-8332928
Address:No.1,Huanghai Yilu.Rizhao,Shandong
Shanghai Yurui Biotechnology(Anyang) Pharmaceutical Co., Ltd
Contact:+86-0372-3662335 +86-0372-3661988
Address:hanling industrial park anyang
Changyi Xinxing Technology Development Co., Ltd.
Contact:0086-510-86651065(Time Zone:8),86651656
Address:94 Yingbinxilu WestRoad, Huangtu Town, Jiangyin City, Jiangsu, China
Hangzhou Pharma & Chem Co.,Ltd.
Contact:+86-571-87040515
Address:No,139Qingchun Rd
Contact:86+21-56421993
Address:3F,BUILDING 10,NO.2889 JINKE ROAD, SHANGHAI.
Doi:10.1016/j.bioorg.2021.104842
(2021)Doi:10.1007/s11164-015-2254-4
(2016)Doi:10.1021/jf902531y
(2010)Doi:10.1021/acsinfecdis.0c00068
(2020)Doi:10.1021/ja01507a026
(1960)Doi:10.1016/S1081-1206(10)62255-7
()
