Journal of the Chemical Society, Dalton Transactions p. 447 - 451 (1981)
Update date:2022-08-11
Topics:
Bhaduri, Sumit
Ghosh, Annoottam
Khwaja, Hanif
The polymer-supported title compound catalyses the homolytic decomposition of ButO2H and its reactions with Me2SO, Bun2S, and cyclohexene to give Me2SO2, Bun2SO, and cyclohexene oxide respectively.Polymer-chain participation in the radical reactions seems to give additional catalytic pathways for the decomposition of ButO2H.Recycling of the polymer-supported complex in the conversion of Me2SO into Me2SO2 results in lower product yields due to the loss of metal ions.Comparative studies between the polymer-supported and the homogeneous systems suggest extra stability for the polymer-anchored, catalytically active species.The diffusion barrier between the reactants in solution and the polymer influences the rates and may be responsible for this extra stability.
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