Journal of the Chemical Society, Dalton Transactions p. 447 - 451 (1981)
Update date:2022-08-11
Topics:
Bhaduri, Sumit
Ghosh, Annoottam
Khwaja, Hanif
The polymer-supported title compound catalyses the homolytic decomposition of ButO2H and its reactions with Me2SO, Bun2S, and cyclohexene to give Me2SO2, Bun2SO, and cyclohexene oxide respectively.Polymer-chain participation in the radical reactions seems to give additional catalytic pathways for the decomposition of ButO2H.Recycling of the polymer-supported complex in the conversion of Me2SO into Me2SO2 results in lower product yields due to the loss of metal ions.Comparative studies between the polymer-supported and the homogeneous systems suggest extra stability for the polymer-anchored, catalytically active species.The diffusion barrier between the reactants in solution and the polymer influences the rates and may be responsible for this extra stability.
View MoreContact:0086-22-23410962
Address:17-201, Ningfuli, Shuishanggongyuandong road,Nankai district, Tianjin, China
Nantong Auxin Electronic Technology Co., LTD
Contact:86-513-88760026
Address:NO.5-1, Aoxin Road, Haian Hi-tech Development Zone, Jiangsu Province, China
Nanjing Fayekong Chemcial Co.,Ltd(expird)
Contact:86-25-58813444
Address:Rm 1503, Unit 1, Building 5, Zijinnanyuan, Nanjing, Jiangsu, China
Weifang Arylchem Chemical Co., LTD
Contact:86-536-5217866
Address:Development Zone, Shouguang, Shandong Province
Synchem Pharma Co.,Ltd(expird)
Contact:+0086-21-61984905-1
Address:Building 60,Zimian Park, LongYang industrial Area, 1515Nong，Yuandong Road Fengxian District, Shanghai ,China
Doi:10.1039/b507655b
(2005)Doi:10.3390/molecules22081275
(2017)Doi:10.1016/S0022-328X(00)86479-7
(1974)Doi:10.1021/jo01094a028
(1959)Doi:10.1021/jo01037a510
(1963)Doi:10.1016/S0040-4039(00)88316-1
(1983)
