Journal of the Chemical Society, Dalton Transactions p. 447 - 451 (1981)
Update date:2022-08-11
Topics:
Bhaduri, Sumit
Ghosh, Annoottam
Khwaja, Hanif
The polymer-supported title compound catalyses the homolytic decomposition of ButO2H and its reactions with Me2SO, Bun2S, and cyclohexene to give Me2SO2, Bun2SO, and cyclohexene oxide respectively.Polymer-chain participation in the radical reactions seems to give additional catalytic pathways for the decomposition of ButO2H.Recycling of the polymer-supported complex in the conversion of Me2SO into Me2SO2 results in lower product yields due to the loss of metal ions.Comparative studies between the polymer-supported and the homogeneous systems suggest extra stability for the polymer-anchored, catalytically active species.The diffusion barrier between the reactants in solution and the polymer influences the rates and may be responsible for this extra stability.
View MoreContact:021-61840961 021-61840962
Address:No.157,Zhuguang Rd, Qingpu, Shanghai, China
Triumph International Development Limilted
website:http://www.jiashengchem.cn/
Contact:+86-536-7971999
Address:Yinhai Road,Shouguang
HANGZHOU ZHONGCHANG SCIENTIFIC CO.,LTD
Contact:+86-571-88932183
Address:Hangzhou
Chemsky(shanghai)International Co.,Ltd.
Contact:0
Address:0
Nanjing distinctions Medical Technology Co., Ltd.
Contact:+86-15996203785 13914714059
Address:nanjing,jiangsu , China
Doi:10.1039/b507655b
(2005)Doi:10.3390/molecules22081275
(2017)Doi:10.1016/S0022-328X(00)86479-7
(1974)Doi:10.1021/jo01094a028
(1959)Doi:10.1021/jo01037a510
(1963)Doi:10.1016/S0040-4039(00)88316-1
(1983)