
Journal of the Electrochemical Society p. 470 - 474 (1987)
Update date:2022-08-11
Topics:
Karlicek Jr.
Mitcham
Ginocchio
Hammarlund
The incomplete pyrolysis of PH//3 is shown to have a significant effect on the growth rate and morphology of InP grown by hydride vapor phase epitaxy. Using ultraviolet absorption spectroscopy to determine the extent of PH//3 pyrolysis, the growth rate of InP is shown to increase with decreasing PH//3 pyrolysis. Incomplete PH//3 pyrolysis is shown to dramatically increase the formation of growth hillocks on LT AN BR 100 RT AN BR InP epitaxial layers. The use of various metal catalysts to expedite PH//3 pyrolysis to eliminate hillock formation during InP growth is described, and a qualitative model of PH//3 induced hillock growth is presented.
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