THERMOLYSE DES HALOGENURES DE PERFLUOROALCANESULFONYLE

DOI: 10.1016/S0022-1139(00)81481-5

Source and publish data:

Journal of Fluorine Chemistry p. 491 - 504 (1984)

Update date:2022-08-11

Topics:

Authors:

Oudrhiri-Hassani, M.

Brunel, D.

Germain, A.

Commeyras, A.

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/S0022-1139(00)81481-5

Perfluoroalkanesulfonyl chlorides FSO2Cl; R_F= CF3, C2F5, C4F9>, decompose thermally to give the corresponding perfluoroalkyl chlorides with evolution of SO2.The latter retards the reaction, but it is catalysed by copper which also inhibits the SO2 effect. 2-methyl-2-nitrosopropane traps the perfluoroalkyl free radicals.In the presence of a perfluoroalkyl iodide FI; R'not equal R_F>, other products, R_FI and R_FCl, are obtained.A free radical chain-mechanism is then suggested.On the other hand, perfluorobutanesulfonyl fluoride is very stable thermally.

Full text of DOI:10.1016/S0022-1139(00)81481-5

Products guided by the article

Product name:Trifluoromethyl iodide

Cas No:2314-97-8

R&D Labs maybe for 2314-97-8

Changzhou Foreign Trade Corp

Contact:+86-519-86623222

Address:29F/D, 99 Yanling West Road, Changzhou, Jiangsu, China
Beijing ZhongDaXinHe Chemical Product Co.,Ltd

Contact:010-52876516

Address:tongzhoubeiyuan
Nanjing Yuance Industry&Trade Co., Ltd.

website:http://www.njyuance.cn/

Contact:+86-25-85439097

Address:B1702, Aoti Bldg, No. 130, Aoti Avenue, Nanjing, China
FUJIAN SHANSHUI CHEMICAL CORP.LTD.

Contact:+86-151-59920036

Address:Jinqiao Gareden, jo@fj-xinyi.com
Shanghai birch chemical technology co.,ltd

Contact:+86-21-54096810

Address:No.2588,Jungong Road,Shanghai,China

Relevant to this article

Doi:10.1016/S0040-4039(01)94386-2
()
Cyclization of natural allene oxide in aprotic solvent: formation of the novel oxylipin methyl cis-12-oxo-10-phytoenoate

Doi:10.1016/j.chemphyslip.2007.04.010
(2007)
Three novel Ni(II), VO(II) and Cr(III) mononuclear complexes encompassing potentially tridentate imine ligand: Synthesis, structural characterization, DNA interaction, antimicrobial evaluation and anticancer activity

Doi:10.1002/aoc.3750
(2017)
Synthesis of activated alkenes bearing the difluoromethylene-phosphonate group: A range of building blocks for the synthesis of secondary difluorophosphonates

Doi:10.1039/a907052d
(1999)
Doi:10.1063/1.1750441
(1939)
The source of follicular androgens in the hamster follicle

Doi:10.1016/0039-128X(80)90111-7
(1980)

Article Doi

THERMOLYSE DES HALOGENURES DE PERFLUOROALCANESULFONYLE

DOI: 10.1016/S0022-1139(00)81481-5

Source and publish data:

Authors:

Article abstract of DOI:10.1016/S0022-1139(00)81481-5

Full text of DOI:10.1016/S0022-1139(00)81481-5

Products guided by the article

R&D Labs maybe for 2314-97-8

Relevant to this article

Cyclization of natural allene oxide in aprotic solvent: formation of the novel oxylipin methyl cis-12-oxo-10-phytoenoate

Three novel Ni(II), VO(II) and Cr(III) mononuclear complexes encompassing potentially tridentate imine ligand: Synthesis, structural characterization, DNA interaction, antimicrobial evaluation and anticancer activity

Synthesis of activated alkenes bearing the difluoromethylene-phosphonate group: A range of building blocks for the synthesis of secondary difluorophosphonates

The source of follicular androgens in the hamster follicle