Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 644 - 646 (1991)
Update date:2022-08-31
Topics:
Tumanskii, B. L.
Kurykin, M. A.
Solodovnikov, S. P.
Bubnov, N. N.
German, L. S.
A study was carried out on the ESR spectra of the spin-adducts of hydroxyalkyl radicals with perfluoro-4-methyl-2-pentene (I) formed upon the photolysis of alcoholic solutions of this perfluoroolefin.The stable conformational positions of the substituents in the spin-adducts depend on the structure of the hydroxyalkyl radicals.The spin-sadducts are annihilated as a consequence of hydrogen atom abstraction as indicated in a preparative experiment.
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