Mechanism of Reactions of Hydrogen Peroxide and Hydroperoxides with Iron(III) Porphyrins. Effects of Hydroperoxide Structure on Kinetics

DOI: 10.1021/ja00204a014

Source and publish data:

Journal of the American Chemical Society p. 8413 - 8420 (1989)

Update date:2022-08-25

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Authors:

Traylor, Teddy G.

Ciccone, Joseph P.

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Article abstract of DOI:10.1021/ja00204a014

The buffer-catalyzed and uncatalyzed reactions of various alkyl hydroperoxides and hydrogen peroxide with chelated protohemin chloride have been studied.The rates of the uncatalyzed reactions show dependence on structure as the catalyzed reactions.The rat

Full text of DOI:10.1021/ja00204a014

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