Tetrahedron p. 2665 - 2670 (1994)
Update date:2022-08-11
Topics:
Barton, Derek H. R.
Beviere, Stephane D.
Hill, David R.
New methodology for the selective transformation of saturated hydrocarbons into ketones/alcohols and alkenes is described. A crucial aspect of this new process is that no reaction solvent is required since the Fe(III) and Cu(II) complexes used are completely soluble in the hydrocarbon substrates. Thus, the large quantity of pyridine, acetic acid or acetonitrile required in previous systems is no longer a prerequisite.
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