Chemistry of Natural Compounds p. 595 - 597 (1986)
Update date:2022-08-18
Topics:
Odinokov, V. N.
Ishmuratov, G. Yu.
Ladenkova, I. M.
Tolstikov, G. A.
A new effective route to the synthesis of 7-oxooctanal has been found which is based on the ozonolysis of the tetrahydropyran-2-yl ether of 7-methyloct-7-en-1-ol - the product of the coupling of the readily available methallyl chloride and the Grignard reagent from the corresponding ether of 5-bromopentan-1-ol.From the 7-oxooctanal has been obtained 9-oxodec-2E-enoic acid - a pheromone of the honeybee Apis melliferana.
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