Journal of Organometallic Chemistry p. 375 - 382 (1989)
Update date:2022-08-10
Topics:
Orsini, F.
Pelizzoni, F.
Vallarino, L. M.
A series of PdII complexes containing various Group V-donors were reduced with diisobutylaluminum hydride and the products screened as potential catalysts for the coupling of representative vinyl- and aryl-trifluoromethanesulfonate substrates to the Reformatsky reagent BrZnCH(CH3)COOtC4H9.The desired coupling product was obtained only with "reduced" dichlorobis(1,1-diphenylphosphino)ferrocene as catalys and 2-naphthyl triflate as the substrate.These results are discussed in terms of the structural features of the reactants and catalyst.
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