Study of the mechanism of ethylene oxidation by palladium(II) complexes containing nitro and/or nitrato ligands in chloroform

DOI: 10.1016/0304-5102(89)85060-6

Source and publish data:

Journal of molecular catalysis p. 167 - 179 (1989)

Update date:2022-08-11

Topics:

Authors:

Beck Beck

Gusevskaya

Stepanov

Likholobov

Nekipelov

Yermakov

Zamaraev

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1016/0304-5102(89)85060-6

Complexes of Pd(NO_n)_2-mCL_mL₂ (where n = 2, 3; m = 0, 1, 2; L = CH₃CN, CD₃CN) were synthesized and their reactivities towards ethylene and propylene oxidation in a chloroform medium were investigated. The detailed mechanism of ethylene oxidation by dinitro- and mono-nitrato complexes of palladium in chloroform solutions was studied by IR and ¹H NMR spectroscopy. The structures and routes of decomposition of the intermediates to reaction end products are proposed.

Full text of DOI:10.1016/0304-5102(89)85060-6

Products guided by the article

Product name:Nitroethylene homopolymer

Cas No:26618-70-2

R&D Labs maybe for 26618-70-2

FUJIAN SHANSHUI CHEMICAL CORP.LTD.

Contact:+86-151-59920036

Address:Jinqiao Gareden, jo@fj-xinyi.com
Hangzhou Mole's Science & Technology Co.,Ltd.(expird)

Contact:+86-571-56880228

Address:15F Guodu development Building, NO.182 Zhaohui Road
Hebei yanxi chemical co.,LTD.

website:https://en.yan-xi.com/

Contact:+86 17531190177--

Address:Zhang zhe, guangzong county, xingtai city, hebei province
Guangzhou Flower's Song Fine Chemical CO,. Ltd

Contact:+86-20-87475199

Address:No.12, Fenghuang 3 Road, Jiulong Industrial Park, Luogang District, Guangzhou. China
Shanghai Balmxy Pharmaceutical Co., Ltd

Contact:0086-21-24206007

Address:Room 402, 15#, No. 909 wangyue Road, shanghai, P. R. China

Relevant to this article

Beckmann and cyclization reactions of δ-oxo-α,β- unsaturated ketoximes obtained from pyrylium salts and hydroxylamine. Formation of 2-aryl(or alkyl)amino-4,6- disubstituted pyrylium salts

Doi:10.1016/S0040-4020(99)00958-8
(1999)
Direct photoreduction and ketone-sensitized reduction of nitrospirobenzopyranindolines by aliphatic amines

Doi:10.1021/jp2005698
(2011)
Molecular Structure and Photochemistry of (E)- and (Z)-Ethyl 3-(2-Indolyl)propenoate. Ground State Conformational Control of Photochemical Behavior and One-Way E -> Z Photoisomerization

Doi:10.1021/jp960907c
(1996)
Studies on -Catalysed Homogeneous Transfer Hydrogenation Reactions; X-Ray Structure of

Doi:10.1039/DT9900001305
(1990)
Copper-catalyzed regioselective chloroamination of alkenes with chlorotrimethylsilane and n-fluorobenzenesulfonimide under microwave-assisted conditions

Doi:10.1246/cl.180937
()
Regioselective radical aminofluorination of styrenes

Doi:10.1002/anie.201406797
(2014)

Article Doi