Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1750 - 1753 (1990)
Update date:2022-08-11
Topics:
Kliger, G. A.
Shuikin, A. N.
Glebov, L. S.
Mikaya, A. I.
Loktev, S. M.
Zaikin, V. G.
In a study of the reaction of 2,2-dimethyl-1-propanol, 2-ethyl-1-hexanol, 2-octanol, and 4-heptanol or 4-heptanone and 2-octanone with aminating agents such as ammonia, dimethylamine, and propylamine in the presence of hydrogen on a fused iron catalyst, we showed that the desired amines are formed through both "imine" and "enamine" mechanisms.
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