MECHANISM OF THE HYDROAMINATION OF ALCOHOLS AND CARBONYL COMPOUNDS ON A FUSED IRON CATALYST

DOI: 10.1007/BF00961521

Source and publish data:

Bulletin of the Academy of Sciences of the USSR Division of Chemical Science p. 1750 - 1753 (1990)

Update date:2022-08-11

Topics:

Authors:

Kliger, G. A.

Shuikin, A. N.

Glebov, L. S.

Mikaya, A. I.

Loktev, S. M.

Zaikin, V. G.

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Article abstract of DOI:10.1007/BF00961521

In a study of the reaction of 2,2-dimethyl-1-propanol, 2-ethyl-1-hexanol, 2-octanol, and 4-heptanol or 4-heptanone and 2-octanone with aminating agents such as ammonia, dimethylamine, and propylamine in the presence of hydrogen on a fused iron catalyst, we showed that the desired amines are formed through both "imine" and "enamine" mechanisms.

Full text of DOI:10.1007/BF00961521

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