
Journal of Organic Chemistry p. 1954 - 1956 (1992)
Update date:2022-08-17
Topics:
Albrecht, Wolfgang
Schwarz, Marion
Heidlas, Juergen
Tressl, Roland
The mechanism of the biotransformations of (S)- and (R,S)-13-hydroxy-(Z,E)-9,11-octadecadienoic acid, 1, into optically pure (R)-δ-decalactone, 12, catalyzed by the yeast Sporobolomyces odorus, was studied, and an oxidation of the secondary hydroxy group followed by an enantioselective reduction of the keto acid intermediate was found to be responsible for the stereochemical outcome.
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