Oxidation of cyclohexene with t-butyl hydroperoxide catalyzed by transition metal oxide clusters

DOI: 10.1016/0022-328X(89)85055-7

Source and publish data:

Journal of Organometallic Chemistry p. C21 - C26 (1989)

Update date:2022-08-16

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Authors:

Zhang, Cuiju

Ozawa, Yoshiki

Hayashi, Yoshihito

Isobe, Kiyoshi

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Article abstract of DOI:10.1016/0022-328X(89)85055-7

Organometallic oxide clusters <(Rhcp')4V6O19> (cp' = η⁵-C5Me5) and <(Rhcp')Cl(CH3CN)2>2 catalyze the oxidation of cyclohexene with t-butyl hydroperoxide to give allylic oxidation products mainly and epoxycyclohexane selectively, respectively.

Full text of DOI:10.1016/0022-328X(89)85055-7

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