Russian Chemical Bulletin p. 1801 - 1803 (1997)
Update date:2022-08-17
Topics:
Suess-Fink
Yan', Hong
Nizova
Stanislas
Shul'pin
Methane is oxidized in aqueous solution with atmospheric oxygen and hydrogen peroxide in a reaction catalyzed by a NaVO3 - pyrazine-2-carboxylic acid system. Methyl hydroperoxide is selectively formed at 50°C. The turnover number of the catalyst after 24 h amounts to 480, and the yield of methyl hydroperoxide is 24% with respect to H2O2. Formaldehyde and formic acid are mainly formed at 120°C.
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