Hydroxylation of Methane by a Sterically Hindered Rhutenium Complex

DOI: 10.1039/c39910000021

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 21 - 22 (1991)

Update date:2022-08-10

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Authors:

Goldstein, Alan S.

Drago, Russell S.

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Article abstract of DOI:10.1039/c39910000021

The sterically crowded cis-(PF6)2 (dmp = 2,9-dimethyl-1,10-phenanthroline, S=Me3CN or H2O) is capable of hydroxylating methane under mild reaction conditions utilizing H2O2 as the primary oxidant; oxidation of this complex with H2O2 is studied spectrophotometrically by UV-VIS and NMR spectroscopy implicating rhutenium (VI) as the active oxidant.

Full text of DOI:10.1039/c39910000021

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