ALLYLIC REARRANGEMENT IN REDISTRIBUTION REACTIONS. THE SYSTEM cis/trans-n-Bu3SnCH2CH=CHCH3/n-Bu2SnCl2

DOI: 10.1016/S0022-328X(00)86645-0

Source and publish data:

Journal of Organometallic Chemistry p. 57 - 62 (1981)

Update date:2022-08-18

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Authors:

Gambaro, Alessandro

Marton, Daniele

Tagliavini, Giuseppe

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Article abstract of DOI:10.1016/S0022-328X(00)86645-0

Allylic rearrangement occurs in the solvent-free redistribution reaction between trans/cis-Bu3SnCH2CH=CHCH3 and Bu2SnCl2: .Subsequent isomerization of I is catalyzed by Bu2SnCl2 (see eq. 2) to an equilibrium mixture of cis-II (72-74percent) trans

Full text of DOI:10.1016/S0022-328X(00)86645-0

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