Tetrahedron Letters p. 6425 - 6428 (1997)
Update date:2022-08-11
Topics:
Asami, Masatoshi
Suga, Takashi
Honda, Kiyoshi
Inoue, Seiichi
A highly enantioselective deprotonation of meso-epoxides was achieved by a catalytic amount of a new chiral lithium amide, derived from (2S,3aS,7aS)-2-(pyrrolidin-1-ylmethyl)octahydroindole, in the presence of excess lithium diisopropylamide to afford the corresponding allylic alcohol derivatives up to 94% ee.
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