Tetrahedron Letters p. 3497 - 3500 (1986)
Update date:2022-08-11
Topics:
Meyer, Gilbert
Rollin, Yolande
Perichon, Jacques
In the solvent N-methyl-2-pyrrolidone the electrochemical reduction of nickel bromide in the presence of potassium iodide, leads to Ni(O) species which are very efficient in the catalytic halogen exchange.Conversion of non-activated aromatic bromides into the corresponding iodides is achieved in good yields, specially when anisole is added to the medium.
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