Structural Chemistry p. 607 - 616 (2017)
Update date:2022-08-16
Topics:
Hordiyenko, Olga V.
Biitseva, Angelina V.
Kostina, Yuliya Yu.
Zubatyuk, Roman I.
Shishkin, Oleg V.
Groth, Ulrich M.
Kornilov, Mikhail Yu.
The simplest o-amidino benzoic acid—2-(amino(imino)methyl)benzoic acid—has been isolated in 23?% yield as a side product of the reaction of phthalonitrile and ammonia along with desired 1-imino-1H-isoindol-3-amine. This amidino acid was fully characterized by nuclear magnetic resonance, IR spectroscopy, mass spectrometry; pKa values were also determined. X-ray diffraction study and quantum chemical calculations revealed that in the solid state it exists as a zwitterion that is stabilized by intermolecular hydrogen bonds.
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