Metal complexes with atropisomeric sulfur ligands in asymmetric hydroformylation: X-ray structure of [Rh2( μ-biphes) ( cod) 2] (H2biphes = 4,4′-biphenanthrene-3,3′-dithiol)

DOI: 10.1016/S0022-328X(97)00151-4

Source and publish data:

Journal of Organometallic Chemistry p. 79 - 87 (1997)

Update date:2022-08-17

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Authors:

Ruiz, Nuria

Aaliti, Abdellatif

Fornies-Camer, Jorge

Ruiz, Aurora

Claver, Carmen

Cardin, Christine J.

Fabbri, Davide

Gladiali, Serafino

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Article abstract of DOI:10.1016/S0022-328X(97)00151-4

The addition of the atropisomeric racemic sulfur compound 4,4′-biphenanthrene-3,3′-dithiol (H₂biphes) to a dichloromethane solution of [{M( μ-OMe)(cod)}₂] (M = Rh, Ir, cod = cycloocta-1,5 -diene) afforded the dithiolate-bridged compl

Full text of DOI:10.1016/S0022-328X(97)00151-4

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