Journal of the Chemical Society, Dalton Transactions p. 240 - 244 (1980)
Update date:2022-08-11
Topics:
McFarlane, H. Christina E.
McFarlane, William
Nash, John A.
The signs and magnitudes of (31)P-(31)P and (31)P-H spin coupling constants in tetraorganobiphosphines RR'PPRR' with Me, Ph, and/or Bu-t as substituents, and in their sulphides and selenides RR'P(X)P(X)RR' (X = S or Se), have been determined by (1)H-<(31)P> heteronuclear double resonance.Large variation in (1)J((31)P-(31)P) arise as a result of changes in the phosphorus hybridization and/or effective nuclear charge, and smaller variations as a result of changes in the position of rotameric equilibrium in the gauche conformers of the biphosphines.
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