Synthesis and reactions of the β-sultone of perfluorovinylsulfonyl fluoride

DOI: 10.1016/0022-1139(93)03003-5

Source and publish data:

Journal of Fluorine Chemistry p. 101 - 104 (1994)

Update date:2022-08-29

Topics:

Authors:

Forohar, Farhad

DesMarteau, Darryl D.

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Article abstract of DOI:10.1016/0022-1139(93)03003-5

Reactions of perfluorovinylsulfonyl fluoride, CF2=CFSO2F (1), with SO3 forms the novel β-sultone cyclo (2) in good yield.Compound 2 undergoes ring-opening upon heating or reaction with fluoride ion to give F(O)C-CF(SO2F)2 (3).Hydrolysis of 3 and 2 yields the new compounds CHF(SO2F)2 (4) and HO3S-CHF-SO2F (5), respectively.

Full text of DOI:10.1016/0022-1139(93)03003-5

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