Thermal and Photochemical Rearrangements of Cyclopropyl Ethers of p-Quinols. Competing Reaction Pathways Leading to Five- and Six-Membered Ring Spirocyclic Ketones

DOI: 10.1021/jo00047a006

Source and publish data:

Journal of Organic Chemistry p. 5568 - 5573 (1992)

Update date:2022-08-30

Topics:

Authors:

Biggs, Timothy N.

Swenton, John S.

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Article abstract of DOI:10.1021/jo00047a006

Cyclopropyl ethers of p-quinols were prepared by reaction of 3''-methylenedispiro<1,3-dioxolane-2,1'-<2,5>cyclohexadiene-4',1''(3''H)-isobenzofuran> and the associated ketone with ethyl diazoacetate/rhodium(II) acetate and diethylzinc/methylene iodide, re

Full text of DOI:10.1021/jo00047a006

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