FIVE VS SIX MEMBERED RING FORMATION IN THE VINYL RADICAL CYCLIZATION

DOI: 10.1016/S0040-4039(00)84995-3

Source and publish data:

Tetrahedron Letters p. 4529 - 4532 (1986)

Update date:2022-08-29

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Authors:

Stork, Gilbert

Mook, Robert

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Article abstract of DOI:10.1016/S0040-4039(00)84995-3

The ratio of methylenecyclopentane to methylenecyclohexane derivatives observed in the vinyl radical cyclization increases with the concentration of substrate and tin hydride.This is interpreted to mean that these cyclizations are under thermodynamic control at low concentrations.

Full text of DOI:10.1016/S0040-4039(00)84995-3

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