Reaction of Hexafluoropropene with Halogenoalkanes

Article abstract of DOI:10.1016/S0022-1139(00)81246-4

Insertion of hexafluoropropene under thermal and/or photochemical conditions occurs into C-H bonds of the halogenomethanes, MeCl, CH2Cl2, CHCl3, MeF, CH2CF2 and CHF2Cl and the fluoroethanes EtF, MeCHF2 and MeCF3, into C-H and C-Cl bonds of the monochloroalkanes EtCl, MeCHFCl, n-PrCl, i-PrCl, t-BuCl and i-BuCl and into C-Cl bonds of allyl chloride and the chloroalkanes CH2ClCH2Cl, MeCHCl2, CH2ClCHCl2 and MeCCl3.