The Pentafluorophenylxenon(II) Cation: +; The First Stable System with a Xenon-Carbon Bond

DOI: 10.1039/c39890000625

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 625 - 627 (1989)

Update date:2022-08-11

Topics:

Authors:

Frohn, Hermann J.

Jakobs, Stephanus

Read Full Text PDF DownLoad Join now for total 90,000,000 free articles

Article abstract of DOI:10.1039/c39890000625

Pentafluorophenylxenon(II) pentafluorophenyltrifluoroborate, ⁺^-, can be prepared analogously to pentafluorophenylhalogen(III) and (V) fluorides, C6F5HalF2 and C6F5HalF4 (with Hal=Br or I), by nucleophilic displacement of fluorine in XeF2 using B(C6F5)3 as an aryl-transfer reagent; the resulting colourless solid with a stable xenon-carbon bond is characterised in solution by (129)Xe and (19)F n.m.r. and chemically as an electrophilic transfer reagent for pentafluorophenyl groups.

Full text of DOI:10.1039/c39890000625

View Article Online / Journal Homepage / Table of Contents for this issue

View Article Online

Products guided by the article

Product name:Pentafluorobenzene

Cas No:363-72-4

R&D Labs maybe for 363-72-4

KA-SHING Business Trade Macau Co., Ltd.

Contact:00853-28430045

Address:23rd Floor, Block 3 La Cite, Areia Preta, Macao
Xinjiang Zhongtai Chemical Co., Ltd.

Contact:+86-991-8788172

Address:NO.78 XISHAN RD.URUMQI，CHINA
Jiangsu Zhenfang Chemical CO.,LTD.(Suzhou Zhenfang Chemical Factory)

Contact:+86-512-69598882

Address:Room1201, Jiayuan Road No.1018, Xiangcheng District, Suzhou, China
STAR SYNTHESIS CO.,LIMITED

Contact:+(852) 301-98033

Address:Flat C, 23/F, Lucky Plaza, 315-321 Lockhart Road, Wan Chai, Hong Kong
CHANGZHOU HANGYU PHARMACEUTICAL TECHNOLOGY CO., LTD

website:http://www.czyys.com

Contact:0086-519-88802789

Address:No.300,Yanling Middle Road, Changzhou, Jiangsu, China

Relevant to this article

Synthesis of derivatives of 3-cyano-6-methyl-5-phenylcarbamoylpyridine-2(1H)-thione and 3-cyano-6-methyl-5-phenyl-carbamoylpyridine-2(1H)-selenone

Doi:10.1023/A:1011981716490
(2001)
Copper(II)-Catalyzed Reactions of Activated Aromatics

Doi:10.1021/jo991509j
(2000)
Preparation of silica-supported sulfate and its application as a stable and highly active solid acid catalyst

Doi:10.1016/j.catcom.2011.01.028
(2011)
Efficient synthesis of 3,4-dihydropyrano[3,2-c]chromenes catalyzed by Ni(II)-functionalized Li⁺-Montmorillonite in a one-pot fashion under solvent-free conditions

Doi:10.1007/s13738-018-1299-x
(2018)
Hydrogen generation from glucose catalyzed by organoruthenium catalysts under mild conditions

Doi:10.1039/c7cc00177k
(2017)
Enantiocomplementary decarboxylative hydroxylation combining photocatalysis and whole-cell biocatalysis in a one-pot cascade process

Doi:10.1039/c9gc00098d
(2019)

Article Doi