The Pentafluorophenylxenon(II) Cation: +; The First Stable System with a Xenon-Carbon Bond

DOI: 10.1039/c39890000625

Source and publish data:

Journal of the Chemical Society. Chemical communications p. 625 - 627 (1989)

Update date:2022-08-11

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Authors:

Frohn, Hermann J.

Jakobs, Stephanus

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Article abstract of DOI:10.1039/c39890000625

Pentafluorophenylxenon(II) pentafluorophenyltrifluoroborate, ⁺^-, can be prepared analogously to pentafluorophenylhalogen(III) and (V) fluorides, C6F5HalF2 and C6F5HalF4 (with Hal=Br or I), by nucleophilic displacement of fluorine in XeF2 using B(C6F5)3 as an aryl-transfer reagent; the resulting colourless solid with a stable xenon-carbon bond is characterised in solution by (129)Xe and (19)F n.m.r. and chemically as an electrophilic transfer reagent for pentafluorophenyl groups.

Full text of DOI:10.1039/c39890000625

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