Support-controlled Switching of Sulphur-Nitrogen Nucleophilicity for Inorganic Solid-supported Alkaline Earth Metal Thiocyanate Reagents

DOI: 10.1039/c39900001213

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Journal of the Chemical Society. Chemical communications p. 1213 - 1214 (1990)

Update date:2022-08-30

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Authors:

Kimura, Takahide

Fujita, Mitsue

Ando, Takashi

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Article abstract of DOI:10.1039/c39900001213

A dramatic change in the sulphur-nitrogen selectivity of the SCN substitution of t-butyl bromide was observed, in addition to a dramatic increase in reaction rate, by simply supporting various alkaline earth metal thiocyanates on various inorganic solids.

Full text of DOI:10.1039/c39900001213

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