Tetrahedron Letters p. 941 - 944 (1981)
Update date:2022-08-11
Topics:
D'Incan, E.
Loupy, A.
Maia, A.
Proton removal of Δ1,9 2-octalone occurs when reacted with NBu4BH4 in aprotic solvents while 1-2 reduction is important with NaBH4 in THF.Both are inhibited when NaBH4 reduction is performed in the presence of amines, leading thus to highly selective formation of saturated alcohols.
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